Synthesis and characterization of isodecyl methacrylate monomer and its copolymer with acrylamide for oil/water separation

Authors

  • Fatima Hekmat Assal Department of Chemistry, College of Science for Women, University of Baghdad
  • ameen hadi mohammed Univesity of Baghdad

DOI:

https://doi.org/10.54153/sjpas.2026.v8i1.1193

Abstract

In this work, isodecyl methacrylate monomer IDMA was synthesized by esterfication of methacrylic acid with isodecylalcohol. IDMA monomer was then copolymerized with acrylamide monomer AAM, in different feed compositions, using free radical polymerization technique. The synthesized IDMA and IDMA/AAM copolymer were characterized by employing proton nuclear magnetic resonance and Fourier transform infrared spectroscopy techniques. Composites of fabricated polymers with metallic mesh, having different pore size, were prepared to examine their performance for separation oil from water. Separation time, reclaimed oil, coating percentage with polymer, and water recovery were directly affected by the composition of copolymer and mesh pore size. Microscopic and photographic images of water, before and after separation by polymers, showed that oil was completely removed from water.

References

1. Fouilloux, H., Qiang, W., Robert, C., Placet, V., & Thomas, C. M. (2021). Multicatalytic Transformation of (Meth) acrylic Acids: a One‐Pot Approach to Biobased Poly (meth) acrylates. Angewandte Chemie International Edition, 60(35), 19374-19382. https://doi.org/10.1002/anie.202106640

2. Ma, J., Zhao, J., Zhang, H., Tian, Z., Liu, Q., Yang, N., & Zhang, W. (2024). Catalytic Mannich reaction of acrylic acid polymers and their application in leather retanning. Reaction Chemistry & Engineering, 9(1), 199-208. https://doi.org/10.1039/D3RE00271C

3. Hu, L., Chee, P. L., Sugiarto, S., Yu, Y., Shi, C., Yan, R., ... & Huang, W. (2023). Hydrogel‐based flexible electronics. Advanced Materials, 35(14), 2205326. https://doi.org/10.1002/adma.202205326

4. Yuk, H., Wu, J., & Zhao, X. (2022). Hydrogel interfaces for merging humans and machines. Nature Reviews Materials, 7(12), 935-952.

https://doi.org/10.1038/s41578-022-00483-4

5. 5. Zhang, H., Wu, S., Chen, W., Hu, Y., Geng, Z., & Su, J. (2023). Bone/cartilage targeted hydrogel: Strategies and applications. Bioactive materials, 23, 156-169.

https://doi.org/10.1016/j.bioactmat.2022.10.028

6. El Sayed, M. M. (2023). Production of polymer hydrogel composites and their applications. Journal of Polymers and the Environment, 31(7), 2855-2879.

https://doi.org/10.1007/s10924-023-02796-z

7. Li, B., Qi, B., Guo, Z., Wang, D., & Jiao, T. (2023). Recent developments in the application of membrane separation technology and its challenges in oil-water separation: A review. Chemosphere, 327, 138528.

https://doi.org/10.1016/j.chemosphere.2023.138528

8. Liu, B., Chen, B., Ling, J., Matchinski, E. J., Dong, G., Ye, X., ... & Zhang, B. (2022). Development of advanced oil/water separation technologies to enhance the effectiveness of mechanical oil recovery operations at sea: Potential and challenges. Journal of Hazardous Materials, 437, 129340.

https://doi.org/10.1016/j.jhazmat.2022.129340

9. Erfani, H., Madhu, N. R., Khodayari, S., Qureshi, M. A., Swetanshu, Singh, P., & Jadoun, S. (2024). Separation and removal of oil from water/wastewater in the oil industry: a review. Environmental Technology Reviews, 13(1), 325-343.

https://doi.org/10.1080/21622515.2024.2343129

10. Bai, X., Yuan, Z., Lu, C., Zhan, H., Ge, W., Li, W., & Liu, Y. (2023). Recent advances in superwetting materials for separation of oil/water mixtures. Nanoscale, 15(11), 5139-5157.

https://doi.org/10.1039/D2NR07088J

11. Dmitrieva, E. S., Anokhina, T. S., Novitsky, E. G., Volkov, V. V., Borisov, I. L., & Volkov, A. V. (2022). Polymeric membranes for oil-water separation: a review. Polymers, 14(5), 980.

https://doi.org/10.3390/polym14050980

12. Zhang, N., Yang, X., Wang, Y., Qi, Y., Zhang, Y., Luo, J., ... & Jiang, W. (2022). A review on oil/water emulsion separation membrane material. Journal of Environmental Chemical Engineering, 10(2), 107257.

https://doi.org/10.1016/j.jece.2022.107257

13. Hussain, A., & Al-Yaari, M. (2021). Development of polymeric membranes for oil/water separation. Membranes, 11(1), 42.

https://doi.org/10.3390/membranes11010042

14. Gong, L., Zhu, H., Wu, W., Lin, D., & Yang, K. (2022). A durable superhydrophobic porous polymer coated sponge for efficient separation of immiscible oil/water mixtures and oil-in-water emulsions. Journal of Hazardous Materials, 425, 127980.

https://doi.org/10.1016/j.jhazmat.2021.127980

15. Zhang, X., Wei, C., Hao, Y. J., Yan, X., Chen, Y., Guo, X. J., & Lang, W. Z. (2023). Spraying-assisted construction of robust polyvinylidene fluoride membrane with superhydrophobic property for water-in-oil emulsions purification. Journal of Environmental Chemical Engineering, 11(4), 110212.

https://doi.org/10.1016/j.jece.2023.110212

16. Kalaleh, H. A., Tally, M., & Atassi, Y. (2015). Preparation of poly (sodium acrylate-co-acrylamide) superabsorbent copolymer via alkaline hydrolysis of acrylamide using microwave irradiation. arXiv preprint arXiv:1502.03639.

https://doi.org/10.48550/arXiv.1502.03639

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Published

2026-04-10

How to Cite

Synthesis and characterization of isodecyl methacrylate monomer and its copolymer with acrylamide for oil/water separation. (2026). Samarra Journal of Pure and Applied Science, 8(1), 198-210. https://doi.org/10.54153/sjpas.2026.v8i1.1193