تقييم راتنجات السيمكاربازايد والثايوسيميكاربازيد المعدلة بالبورون كمثبطات لتآكل سبائك الصلب الكاربوني في البيئة الحامضية

المؤلفون

  • مصطفى فتحي علي
  • تحسن علي صاكي Department of Chemistry, Collage of Science, University of Basra
  • هادي زيارة محمد

DOI:

https://doi.org/10.54153/sjpas.2025.v7i1.854

الكلمات المفتاحية:

سيميكاربازايد-فورمالديهايد، ثايوسيميكاربازايد-فورمالديهايد، حامض البوريك، مثبطات التآكل، الراتنجات

الملخص

إن القلق بشأن تأثير التآكل على السلامة الهيكلية للأسطح المعدنية طويل الأمد. لذا تُستخدم مثبطات التآكل بشكل روتيني في الأنشطة الصناعية. اعتمد هذا البحث على تحضير نوعين من المثبطات: راتنجات السيميكاربازيد-فورمالدهايد المعدلة بالبورون (SFB) المشتقة من السيميكاربازيد، والفورمالدهيد، وحامض البوريك، والمثبط الآخر راتنجات الثايوسيميكاربازيد-فورمالدهايد المعدلة بالبورون (TSFB) المشتق من الثايوسيميكاربازيد، والفورمالدهيد، وحامض البوريك، وتمت دراستها باستخدام تقنيات FTIR وTGA. تم تقييمها كمثبطات لتآكل سبائك الفولاذ الكاربوني في بيئة حامضية اكالة من حامض الهيدروكلوريك 0.1 مولاري عند درجات حرارة متعددة (25، 35، 45، 55) درجة مئوية وبتراكيز مختلفة لكلا المثبطين كل على حدة، حيث أعطى (SFB) أفضل كفاءة تثبيط عند تركيز 4 جزء بالمليون بينما أفضل كفاءة تثبيطية كانت للـ (TSFB) عندما كان تركيزه 10 جزء بالمليون.

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التنزيلات

منشور

2025-03-30

كيفية الاقتباس

تقييم راتنجات السيمكاربازايد والثايوسيميكاربازيد المعدلة بالبورون كمثبطات لتآكل سبائك الصلب الكاربوني في البيئة الحامضية. (2025). مجلة سامراء للعلوم الصرفة والتطبيقية, 7(1), 102-123. https://doi.org/10.54153/sjpas.2025.v7i1.854

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